Caribbean Industrial Research Institute, Calibration Laboratory, University of the West Indies, St. Augustine, Trinidad and Tobago
The Polymer Electrolyte Membrane fuel cell is one of the most promising green technologies for addressing portable, as well as transportation power needs. However, the science behind the fuel cell, in many regards, is still an enigma, and even more so, with the vast numbers of novel materials created annually; designed to offset issues related to durability, conductivity, cost- effectiveness and ...
R. Pushpangadan, A. Soman, Arundas R., N. G. Thoppan, S. P. Duttagupta
Department of Electrical Engineering, Indian Institute of Technology Bombay, Mumbai, Maharashtra, India
College of Engineering, Munnar, Kerala, India
PEM fuel cells are very promising for portable applications. A key component of fuel cell is the flow field plate through which hydrogen will reach the anode, oxygen will reach the cathode and electron collection. Flow field plate made of silicon is not a good electrical conductor , so electrical contacts has to be attached to the Gas Diffusion Layer (GDL) for taking the power to outside ...
T. Machado Amorim , C. Allély, J. Caire
Arcelor Mittal Research, Maizieres-les-Metz, France
ENSEEG, Grenoble, France
The corrosion at cut-made edges is significant due to the anode to cathode surface ratio in this region. The major problems are the risks of red rust appearance at the exposed steel surface, and the risks of paint delamination in case of insufficient corrosion protection. The work presented here focuses on the development of a 2D FEM model simulating a steady state corrosion situation at a cut ...
Modeling the Effect of Discrete Distributions of Platinum Particles in the PEM Fuel Cell Catalyst Layer
C.F. Cetinbas, A.K. Prasad, S.G. Advani
Center for Fuel Cell Research, Department of Mechanical Engineering, University of Delaware, Newark, DE, USA
University of Delaware, Newark, DE, USA
In this study, the basic catalyst layer (CL) structure, consisting of carbon-supported Pt particles (C|Pt) and an ionomer binder, is investigated numerically by using COMSOL. The significance of modeling discrete Pt particles on the carbon support is highlighted by comparing the cell performance results to the case in which the Pt is assumed to be distributed uniformly over the carbon support as ...
A. Aman, R. Gentile, Y. Xu, N. Orlovskaya
Department of Mechanical, Materials and Aerospace Engineering, University of Central Florida, Orlando, FL, USA
Fuel cells are devices that convert chemical energy of a fuel into electrical energy through electrochemical processes. One of the types of fuel cell is the Solid Oxide Fuel Cell (SOFC) that uses solid ceramics for electrolytes. Numerical simulation involves constructing a mathematical model of the SOFC and use of specifically designed software programs that allows the user to manipulate the ...
J. Bouhattate, X. Feaugas, and S. Frappart
Laboratoire d’Etudes des Matériaux en Milieux Agressifs,
Université de La Rochelle, La Rochelle, France
V&M France, CEV, Aulnoye-Aymeries, France
Hydrogen Embrittlement (HE) is one of the mechanisms responsible for premature failure of structures. In the context of environmental sustainability, it is compelling to improve or conceive new processes and/or new materials capable of reducing fracture induced by HE. We analyzed the influence of the oxide layer on the permeability of hydrogen. This investigation was carried on as a correlative ...
Screening Effects in Probing the Electric Double Layer by Scanning Electrochemical Potential Microscopy
R.F. Hamou, P.U. Biedermann, A. Erbe, and M. Rohwerder
Max-Planck-Institut für Eisenforschung GmbH, Düsseldorf, Germany
A computational method is developed to study probing the electric double layer by Scanning Electrochemical Potential Microscopy. The model is based on a modified Poisson- Boltzmann equation, which takes into account steric effects. We investigated the effect of metallic apex protrusion and the Open Circuit Potential (OCP) of the tip on the probed potential. A clear electrostatic screening effect ...
F. Daouda, J. Hamelin, P. Benard, S. Kumar Natarajan 
Insitut de recherche sur l'hydrogène, Université du Québec à Trois-Rivières, Trois-Rivières, Québec, Canada
We present a novel multi-layered electrode fabrication technique for polymer electrolyte membrane fuel cells (PEMFCs). This method consists of alternate layers of Pt deposition (0.05 mg/cm²) by sputtering on the painted multi-walled carbon-Nafion layer (CNL) with larger concentration of catalyst particles closer to the membrane. Parametric models were developed and validated by experimental ...
C. Wang, Y. Song, Y. Parikh, and J.H. Yang
Department of Mechanical & Materials Science Engineering, Florida International University, Miami, Florida, USA
Enzymatic biofuel cells (EBFCs) are miniature implantable power sources, which use enzymes as catalysts to perform redox reaction with biological fuels such as glucose. In this study, we focused on a three dimensional EBFC chip with highly dense micro-electrode arrays, fabricated by carbon-micro-electro-mechanical-system (C-MEMS) techniques. Glucose oxidase (GOx) is immobilized on anodes for the ...
B. Bozzini, S. Maci, I. Sgura, R. Lo Presti, and E. Simonetti
Dipartimento di Ingegneria dell’Innovazione, Università del Salento, Lecce, Italy
Dipartimento di Matematica, Università del Salento, Lecce, Italy
ENEA Casaccia, Dipartimento TER, Centro Ricerche Casaccia, S. Maria di Galeria, Roma, Italy
This paper describes the numerical modeling of a key material-stability issue within the realm of Molten Carbonate Fuel Cells (MCFC). The model describes the morphological and attending electrocatalytic evolution of porous NiO electrodes and is apt to predict electrochemical observables that can be recorded during Fuel Cell operation. The model has been validated with original experimental data ...